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              名稱:二茂鐵甲酸
               

              純度:99% 包裝:25kg/桶
              結構式
                  

              CAS: 1271-42-7
              分子式:C11H10FeO2
              分子量: 230.04
               
              中文名稱: 二茂鐵甲酸
               
              英文名稱: ferrocenecarboxylic acid
                                    ferrocene carboxylic acid
                                    ferrocenecarboxylicacid
               
              性狀描述: 黃色粉末。熔點208-212℃。
               
              用途: 可用于不對稱有機合成催化劑,燃燒控制劑或調節劑,在高分子材料中也可作光敏劑,穩定劑和改良劑。

              其它信息:

              Material Safety Data Sheet 
              Ferrocenecarboxylic acid  二茂鐵甲酸
              Section 1 - Chemical Product and Company Identification 
              MSDS Name: Ferrocenecarboxylic acid 
              Catalog Numbers: 34823-0000, 34823-0010, 34823-0100 
              Synonyms: Carboxyferrocene 
              Company Identification:  Acros Organics BVBA
              Janssen Pharmaceuticalaan 3a
              2440 Geel, Belgium 
              Company Identification: (USA) Acros Organics
              One Reagent Lane
              Fair Lawn, NJ 07410 
              For information in the US, call:  800-ACROS-01
              For information in Europe, call: +32 14 57 52 11
              Emergency Number, Europe: +32 14 57 52 99
              Emergency Number US: 201-796-7100
              CHEMTREC Phone Number, US:  800-424-9300
              CHEMTREC Phone Number, Europe:  703-527-3887 
              Section 2 - Composition, Information on Ingredients 
              CAS# Chemical Name: % EINECS#
              1271-42-7 Ferrocenecarboxylic acid 97% 215-040-6
              Hazard Symbols: XN 
                 
              Risk Phrases: 22 36/37/38 
              Section 3 - Hazards Identification 
              EMERGENCY OVERVIEW 
              Harmful if swallowed. Irritating to eyes, respiratory system and skin. 
              Potential Health Effects
              Eye: Causes eye irritation. 
              Skin: Causes skin irritation. May be harmful if absorbed through the skin. 
              Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. 
              Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. 
              Chronic: 
              Section 4 - First Aid Measures 
              Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. 
              Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. 
              Ingestion: Get medical aid. Wash mouth out with water. 
              Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. 
              Notes to Physician: Treat symptomatically and supportively. 
              Section 5 - Fire Fighting Measures 
              General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. 
              Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
              Section 6 - Accidental Release Measures 
              General Information: Use proper personal protective equipment as indicated in Section 8. 
              Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Do not let this chemical enter the environment. 
              Section 7 - Handling and Storage 
              Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation. 
              Storage: Store in a cool, dry place. Store in a tightly closed container. 
              Section 8 - Exposure Controls, Personal Protection 
              Engineering Controls: 
               Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 
              Exposure Limits
               CAS# 1271-42-7:
               
              Personal Protective Equipment 
              Eyes: Wear chemical splash goggles. 
              Skin: Wear appropriate protective gloves to prevent skin exposure. 
              Clothing: Wear appropriate protective clothing to prevent skin exposure. 
              Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
               
              Section 9 - Physical and Chemical Properties 
               
              Physical State: Powder
              Color: yellow to orange - brown 
              Odor: Not available 
              pH: Not available 
              Vapor Pressure: Not available 
              Viscosity: Not available 
              Boiling Point: Not available 
              Freezing/Melting Point: 210 deg C(decom) 
              Autoignition Temperature: Not available 
              Flash Point: Not available 
              Explosion Limits: Lower: Not available
              Explosion Limits: Upper: Not available
              Decomposition Temperature: Not available
              Solubility in water: Not available
              Specific Gravity/Density: 
              Molecular Formula: C11H10FeO2 
              Molecular Weight: 229.91 
              Section 10 - Stability and Reactivity 
              Chemical Stability: Stable. 
              Conditions to Avoid: Incompatible materials, dust generation. 
              Incompatibilities with Other Materials Strong oxidizing agents. 
              Hazardous Decomposition Products Carbon monoxide, carbon dioxide, oxides of iron. 
              Hazardous Polymerization Will not occur. 
              Section 11 - Toxicological Information 
              RTECS#: CAS# 1271-42-7: None listed
               
              LD50/LC50: RTECS: Not available. 
              Carcinogenicity: Ferrocenecarboxylic acid - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
               
              Other: The toxicological properties have not been fully investigated. 
              Section 12 - Ecological Information 
              Other: Do not empty into drains.
               
              Section 13 - Disposal Considerations 
              Dispose of in a manner consistent with federal, state, and local regulations. 
              Section 14 - Transport Information 

               IATA  IMO  RID/ADR 
              Shipping Name:  Not regulated.  Not regulated.  Not regulated. 
              Hazard Class:    
              UN Number:    
              Packing Group:    

              Section 15 - Regulatory Information 
              European/International Regulations
              European Labeling in Accordance with EC Directives
              Hazard Symbols: XN 
              Risk Phrases:
              R 22 Harmful if swallowed. 
              R 36/37/38 Irritating to eyes, respiratory system and skin. 
               
              Safety Phrases:
              S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
              S 37/39 Wear suitable gloves and eye/face protection.  
               
              WGK (Water Danger/Protection)
              CAS# 1271-42-7: Not available

              TSCA
              CAS# 1271-42-7 is not listed on the TSCA Inventory. It is for research and development use only. 


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